NFPA HAZARD HMIS HAZARD WHMIS HAZARD Persistence and degradability 11-52-0 Monoammonium Phosphate (7783-28-0) Persistence and degradability Biodegradability in water: no data available. Symptoms may include nausea, vomiting and diarrhea. The following treatments should be considered for the specific group(s) of phosphate salts found in this product: 4. 2B, H320 Inhalation : No known significant effects or critical hazards. Lee et al./Monoammonium phosphate inhalation 237 arrhythmia and haemodynamic decompensation. Specific Gravity: 1.80 for Monoammonium Phosphate pH: 4.2 % Volatile by volume @ 21C (70F): 0 Boiling Point: No information found Mono Ammonium Phosphate Get medical attention if Diammonium phosphate is more toxic than monoammonium phosphate but less toxic than urea. Physical Hazards: Slippery when wet. Irritating to skin. Skin : Practically non-toxic in contact with skin. Persistence and degradability AGROPELL by Simplot Ammonium Phosphate Sulfate 16-20-0 with 13% Sulfur Persistence and … 11-52-0 Monoammonium Phosphate (7783-28-0) LC50 fish 1 155 ppm (96 h; Pimephales promelas) TLM fish 1 100 - 1000,96 h; Pisces TLM other aquatic organisms 1 100 - 1000,96 h 12.2. % GHS-US classification Monoammonium Phosphate 7722-76-1 Eye Irrit. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. 4 0 obj Monoammonium Phosphate (7722-76-1) Persistence and degradability Biodegradability in water: no data available. <>>> See Section 3 for chemical specific data. MAP, Mono-ammonium Phosphate Page 5 of 5 Exposure Limits: See sections 8 & 12 EPA: Approved pursuant to the HSNO Act 1996, Approval number HSR002768. {��������w��������������vw��� Persistence and degradability 11-52-0 Mono-Ammonium Phosphate Persistence and degradability Not established. <> Monoammonium phosphate (MAP) is a widely used source of phosphorus (P) and nitrogen (N) in fertilizer industry. In Beverage. Inhalation of monoammonium phosphate and sodium bicarbonate can cause mild irritation to the nose, throat, and lungs and results in symptoms like shortness of breath and coughing. Ammonium dihydrogen phosphate Revision Date 23-Jan-2018 Monoammonium phosphate 7722-76-1 >95 4. endobj --Potassium salts have a hypothetical risk of hyperkalemia which can cause cardiac arrhythmia. But while they get the job done, they leave quite a mess behind. Toxicity: Non-toxic. 58 / Monday, March 26, 2012 / Rules and Regulations 03/05/2020 EN (English) 6/6 SECTION 15: Regulatory information 15.1. Ƌ���VT�� /+.�F�������NU���W�;f������;���vwV Monoammonium phosphate is one of the chemicals included in commercial crystal growing kits because it is safe and practically foolproof for producing a mass of crystals quickly. 12.2. �� �aB�L75�*Dh\}��((��SkC�P/Sy#��b�AπFe2,uX����Z!0�S���A�*CEb@J C�� �J>�K��f0�.�;D����C �ķ �N The toxic effect of diammonium phosphate was more pronounced than that of urea. endobj As a result they can cause skin and eye irritation, throat discomfort, and some difficulty breathing if inhaled. According to the diammonium phosphate MSDS from CF Industries, Inc., decomposition starts as low as 70 °C: "Hazardous Decomposition Products: Gradually loses ammonia when exposed to air at room temperature. Monoammonium Phosphate (M.A.P.) Toxicity No additional information provided for this product. Monoammonium Phosphate, Tech. endstream endobj 1275 0 obj <>stream 11-52-0 MonoAmmonium Phosphate Safety Data Sheet according to Federal Register / Vol. diarrhea and, thus, not cause any systemic toxicity. Monoammonium Phosphate can be used as Leavening agent in food such as in tomatoes, lemons, oranges, apples, cheese and yogurt. h�bbd```b``:"��� ��D���HV6��T0�L��}`��� <>/XObject<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 612 792] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> ... manifesting clinical signs of toxicity. h�b```� endobj US Federal regulations 11-52-0 MonoAmmonium Phosphate Not listed on the United States TSCA (Toxic Substances Control Act) inventory 1303 0 obj <>stream h޼VmO�0�+�*��q*�J}�P�2�v�(B�HiR%a��~wvZVX�.>�w�s�st #\t������-Q�Dsk�@iT�̷�O��� �J�����6D��� 0a��)�8"�P�0��L�m^l�����nk��Su5����z��tn-���d�2E�?׋dU=��to�M�~��g���q�K"�Y5�Oa����#�A�����xch�H�t:��c�N�8M��l��草WI�&R�i�����*��� `̥H�U^��u�B�^/���4��w�H)�0�����EQ�?I{c�p�(Z+��9�`�}�sv%���-��;�����ձ�=x~׶mF�d����Y�p�������Ƌ�l�Z>�D�Ѹ4x�-P.�e�`��$�ge���IQVÇ�h���@F��M\�p�S�1���� Toxicity data Ingredient name Monoammonium Phosphate LD50 LD50 >2000 mg/kg >5000 mg/kg Oral Dermal Rat Rabbit Test Result Route Species Eyes : Irritating to eyes. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. Some byproduct monoammonium phosphate made with furnace acid has a grade of 12-61-0 and is used mainly in production of liquid fertilizers. The acute toxicity reported on this page is of the pure chemical ingredient only and may not reflect the acute toxicity of individual pesticide products. SDS Revision Date: 02/21/2017 Page 8 of 9 12. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. When a person is exposed to high concentrations of these chemicals in the air, such as might occur after the use of a fire extinguisher in an enclosed space, monoammonium phosphate and ammonium sulfate have mild irritant effects. Appearance: Gray, tan or brown granules or powder. Monoammonium Phosphate uses as follows: In Food. :201 4/11 5.2. The toxic effect of diammonium phosphate resulted in a sudden fall of hematological parameters--Hb, red blood cell count, Hct--at higher concentrations, and at lower concentrations gradual decreases were seen over comparatively longer durations. Chemosphere. The crystal shape is perfect for green "emerald" crystals. To view acute toxicity of individual products, click on 'View Products' link in the 'Chemical Identification' section above. SSP 11-52-0 Monoammonium Phosphate Coated with AVAIL Not listed on the United States TSCA (Toxic Substances Control Act) inventory All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for: Proprietary CAS No % 15.2. It also has significant uses in optics and electronics. Decomposes to ammonia and monoammonium phosphate at around 70 °C (158 °F). ADP is a major ingredient of agricultural fertilizers and some fire extinguishers. <> 12.1. Not established. 2017 May;174:515-523. doi: 10.1016/j.chemosphere.2017.02.006. Ammonium nitrate, monoammonium phosphate and ammonium sulphate are similar in toxicity and much safer than anhydrous ammonia, aqua ammonia or urea. 12.3. (MAP) Monoammonium phosphate Safety Data Sheet 201 04/30/2015 EN (English) SDS Ref. Ecological information 12.1. See www.epa.govt.nz for approval controls. Epub 2017 Feb 3. Increasing urinary phosphate excretion helps to lower serum phosphate levels, but in severe hyperphosphataemia with … Doses greater than 10 grams hypothetically may cause systemic toxicity. 1288 0 obj <>/Filter/FlateDecode/ID[<33C1B0E70CE81D4498E21C7D52E63F6B>]/Index[1271 33]/Info 1270 0 R/Length 92/Prev 183483/Root 1272 0 R/Size 1304/Type/XRef/W[1 3 1]>>stream Monoammonium phosphate Iron ammonium phosphates Aluminum ammonium phosphates Ammonium sulfate Magnesium ammonium phosphates Fluorides, as F ... Ingestion: Low to moderate degree of toxicity by ingestion. H��W�N�H}���G{�i���B�:�J�2�>0�� D" ������j� `�2�����S�OU���E>��vv��. 3 0 obj The pure chemical yields clear crystals, but you can add food coloring to get any color you desire. Ammonium Sulfate Ingestion: causes irritation to the gastrointestinal tract. Ammonium phosphate dry chemical fire extinguishers are an essential tool for putting out fires. You must clean up as soon as possible after the fire extinguisher is discharged. 1. dU�4���~�{w@)g_��SRQ����`�ј���m�C�P�������v�A�����Ĩ��uq�jJ��$O�X�d��@I]6�. Get medical attention if symptoms occur. %���� Cancer Information: 2,4-D This chemical may cause irritation and itching. FIRST AID MEASURES 77, No. Treatment should take into consideration both anionic and cation portion of the molecule. The values listed below represent the percentages of ingredients of unknown toxicity. 1:550 1956]. %%EOF Q�S�NՂ�K�2�x6Y��jwN��:)�bw�_���"n��� 8�����$5�����~j�"�0�T?����wĽ���H���������H�����G� No. MONOAMMONIUM PHOSPHATE Page 2 of 9 http://www.innophos.com/msds/0000031680000100010056E00017.htm 3/18/2008 --Ammonium salts have a hypothetical risk of ammonia toxicity. Aquatic Ecotoxicity Ingredient 96 hr LC50 fish, mg/l 48 … stream Monoammonium phosphate, NH 4 •H 2 PO 4, crystallizes in quadratic prisms. 1 0 obj 0 Decomposition of sodium hypochlorite takes place within a few seconds with the following salts: ammonium acetate, ammonium carbonate, ammonium nitrate, ammonium oxalate, and ammonium phosphate [Mellor 2 Supp. Acute oral toxicity < 10% Acute dermal toxicity < 10% Acute inhalation toxicity < 10% Acute aquatic toxicity < 10% . Pre-Existing Medical Conditions: Pre-existing respiratory disorders may be aggravated by exposure to this material. Dizziness and headache are also possible. ��G~�P�# f���bȣ�y8�v%��$����9���hoi�J:Z�u��w.֩�=8� �؇�� Yԇ�*�ѤlW1 �Kw[�Zn69u���/F���,#�i��6�^� ���_ One component, monoammonium phosphate, has the potential to cause minor skin irritation and is classed in the same category as acetone. Odor: Monoammonium Phosphate has faint acid odor. In addition to calcium levels, ammonia and phosphate levels should be monitored. Monoammonium Phosphate can be used in beverage. Odour: Slight ammonia odour. Special hazards arising from the substance or mixture Product Name: Feed MAP ( Monoammonium Phosphate) Page 4 of 5 Section XII – Ecological Information Ecotoxicity: EPA Ecological Toxicity rating : Slightly toxic to practically non-toxic to aquatic organisms based on the Federal Insecticide Fungicide and Rodenticide Act (FIFRA) acute toxicity ratings. &�QjV(�K����jw��������:�Ag��E��2�F�(o�Lf��=9[���z�fW�=�g+��fOs�g�\�t���W��!��m,ZUJ���/�+Y֡�W ҅�Dt x��\mo�6�n��Aw��,�IT[pm_�Cܦ���!�q��[o����f�/"wEQ�7�C��v5��g��������Ū������jqq{uY|�? Slightly to Moderately Toxic No 2. 2 0 obj Several liquid ammonium phosphate fertilizer tanks have ruptured due to inadequate tank design and maintenance. The chemical is used in animal feed, plant fertilizers, and is found in some dry chemical fire extinguishers. Physical Form: Solid. Residual effects of monoammonium phosphate, gypsum and elemental sulfur on cadmium phytoavailability and translocation from soil to wheat in an effluent irrigated field. 1271 0 obj <> endobj endstream endobj startxref This Safety Data Sheet was updated on the date shown and supersedes all previous versions. Nongranular (powder) monoammonium phosphate is used in formulations for granular NP and NPK fertilizers, which it can react with additional ammonia and aid … %PDF-1.5 11-24 Mono Ammonium Phosphate Feed Grade Chemical Name and Synonyms C.A.S. �N����Al>�Fv ��,������ $����/�g� Os ? Various fertilizers differ in toxicity. It presents little toxicity unless large amounts are ingested, in which case, vomiting and diarrhea are likely. Toxicity Monoammonium Phosphate (7722-76-1) LC50 fish 1 155 ppm (96 h; Pimephales promelas) 12.2. If you spill it on your skin, wash it off with water. Appearance: Monoammonium Phosphate is brilliant white crystals or granules. Solubility: Mono Ammonium Phosphate is soluble 1 g/2.5 ml water. �3/�R�&j�V:����ݿ%��&Eg���Cf������'3�=A�}��n^4���0�-FX��؟�p5�.Z췘�(5Okn�n��F$��{���w}��Y���p Most dry fire extinguishers use compressed nitrogen gas to propel a yellow fire-suppressing powder over the flames. Grade LidoChem, Inc. SAFETY DATA SHEET Page: 6 of 8 Section 14 - Transport Information Section 15 - Regulatory Information This product does NOT contain any products considered hazardous under the Federal OSHA HazCom. endstream endobj 1272 0 obj <>/Metadata 27 0 R/Pages 1269 0 R/StructTreeRoot 34 0 R/Type/Catalog>> endobj 1273 0 obj <>/MediaBox[0 0 612 792]/Parent 1269 0 R/Resources<>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 1274 0 obj <>stream %PDF-1.5 %���� 12.1. Wash thoroughly after handling. Monoammonium phosphate is generally recognized as safe when used in accordance with good manufacturing practice. 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They can cause skin and eye irritation, throat discomfort, and some difficulty if... Data Sheet according to Federal Register / Vol must clean up as soon as possible after the fire is! 3/18/2008 -- ammonium salts have a hypothetical risk of hyperkalemia which can cause skin and irritation... The toxic effect of diammonium phosphate is more toxic than monoammonium phosphate ( ). Name and Synonyms C.A.S 11-52-0 Mono-Ammonium phosphate Persistence and degradability Biodegradability in water: no Data available aqua ammonia urea!